FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2078019355> ?p ?o ?g. }

• W2078019355 endingPage "936" @default.
• W2078019355 startingPage "925" @default.
• W2078019355 abstract "Abstract Summary: Potential sources of inhibition have been investigated via in situ Fourier transform – near infra‐red (FT‐NIR) and off‐line 1 H NMR spectroscopy in the RAFT/MADIX bulk polymerization of vinyl acetate (VA) in the presence of an O ‐isopropyl xanthate, i.e. methyl (isopropoxycarbonothioyl)sulfanyl acetate. The very high reactivity of the vinyl acetate propagating radical makes it vulnerable to oxygen, by‐products generated during the xanthate synthesis, and stabilizers present as impurities. These impurities induce strong and variable inhibition periods in the polymerization. In addition, the MADIX process, using xanthates as reversible chain transfer agents, has been confirmed to be an efficient method for living VA polymerization. Congruent data are obtained when the monomer consumption with time is followed via both 1 H NMR and in situ FT‐NIR spectroscopy. The xanthate‐mediated polymerization of VA exhibits no retardation effects and excellent control of the molecular weight distribution can be achieved, leading to poly(VA) of molecular weights exceeding 50 000 g · mol −1 with relatively low polydispersities. image" @default.
• W2078019355 created "2016-06-24" @default.
• W2078019355 creator A5003954971 @default.
• W2078019355 creator A5004482996 @default.
• W2078019355 creator A5016059121 @default.
• W2078019355 creator A5067402087 @default.
• W2078019355 date "2004-04-26" @default.
• W2078019355 modified "2023-10-18" @default.
• W2078019355 title "A Detailed On-Line FT/NIR and1H NMR Spectroscopic Investigation into Factors Causing Inhibition in Xanthate-Mediated Vinyl Acetate Polymerization" @default.
• W2078019355 cites W1964918647 @default.
• W2078019355 cites W1966863664 @default.
• W2078019355 cites W1976051615 @default.
• W2078019355 cites W1982863731 @default.
• W2078019355 cites W1985631236 @default.
• W2078019355 cites W2006115982 @default.
• W2078019355 cites W2008443986 @default.
• W2078019355 cites W2010018976 @default.
• W2078019355 cites W2023853453 @default.
• W2078019355 cites W2027761597 @default.
• W2078019355 cites W2029255146 @default.
• W2078019355 cites W2032373909 @default.
• W2078019355 cites W2036333105 @default.
• W2078019355 cites W2039437534 @default.
• W2078019355 cites W2043522763 @default.
• W2078019355 cites W2054178986 @default.
• W2078019355 cites W2055393399 @default.
• W2078019355 cites W2072047249 @default.
• W2078019355 cites W2072386022 @default.
• W2078019355 cites W2088490639 @default.
• W2078019355 cites W2089888176 @default.
• W2078019355 cites W2135649714 @default.
• W2078019355 cites W2139414379 @default.
• W2078019355 cites W2144122182 @default.
• W2078019355 cites W2146580600 @default.
• W2078019355 cites W2150184000 @default.
• W2078019355 cites W2952053429 @default.
• W2078019355 doi "https://doi.org/10.1002/macp.200300179" @default.
• W2078019355 hasPublicationYear "2004" @default.
• W2078019355 type Work @default.
• W2078019355 sameAs 2078019355 @default.
• W2078019355 citedByCount "94" @default.
• W2078019355 countsByYear W20780193552012 @default.
• W2078019355 countsByYear W20780193552013 @default.
• W2078019355 countsByYear W20780193552014 @default.
• W2078019355 countsByYear W20780193552015 @default.
• W2078019355 countsByYear W20780193552016 @default.
• W2078019355 countsByYear W20780193552017 @default.
• W2078019355 countsByYear W20780193552018 @default.
• W2078019355 countsByYear W20780193552019 @default.
• W2078019355 countsByYear W20780193552020 @default.
• W2078019355 countsByYear W20780193552022 @default.
• W2078019355 countsByYear W20780193552023 @default.
• W2078019355 crossrefType "journal-article" @default.
• W2078019355 hasAuthorship W2078019355A5003954971 @default.
• W2078019355 hasAuthorship W2078019355A5004482996 @default.
• W2078019355 hasAuthorship W2078019355A5016059121 @default.
• W2078019355 hasAuthorship W2078019355A5067402087 @default.
• W2078019355 hasConcept C111998727 @default.
• W2078019355 hasConcept C121120078 @default.
• W2078019355 hasConcept C15920480 @default.
• W2078019355 hasConcept C166940927 @default.
• W2078019355 hasConcept C178790620 @default.
• W2078019355 hasConcept C185592680 @default.
• W2078019355 hasConcept C188027245 @default.
• W2078019355 hasConcept C2776093513 @default.
• W2078019355 hasConcept C2776821766 @default.
• W2078019355 hasConcept C34594497 @default.
• W2078019355 hasConcept C44228677 @default.
• W2078019355 hasConcept C521977710 @default.
• W2078019355 hasConcept C9132879 @default.
• W2078019355 hasConceptScore W2078019355C111998727 @default.
• W2078019355 hasConceptScore W2078019355C121120078 @default.
• W2078019355 hasConceptScore W2078019355C15920480 @default.
• W2078019355 hasConceptScore W2078019355C166940927 @default.
• W2078019355 hasConceptScore W2078019355C178790620 @default.
• W2078019355 hasConceptScore W2078019355C185592680 @default.
• W2078019355 hasConceptScore W2078019355C188027245 @default.
• W2078019355 hasConceptScore W2078019355C2776093513 @default.
• W2078019355 hasConceptScore W2078019355C2776821766 @default.
• W2078019355 hasConceptScore W2078019355C34594497 @default.
• W2078019355 hasConceptScore W2078019355C44228677 @default.
• W2078019355 hasConceptScore W2078019355C521977710 @default.
• W2078019355 hasConceptScore W2078019355C9132879 @default.
• W2078019355 hasIssue "7" @default.
• W2078019355 hasLocation W20780193551 @default.
• W2078019355 hasOpenAccess W2078019355 @default.
• W2078019355 hasPrimaryLocation W20780193551 @default.
• W2078019355 hasRelatedWork W160554924 @default.
• W2078019355 hasRelatedWork W1988899632 @default.
• W2078019355 hasRelatedWork W2067457827 @default.
• W2078019355 hasRelatedWork W2133456147 @default.
• W2078019355 hasRelatedWork W2377052952 @default.
• W2078019355 hasRelatedWork W2887495713 @default.
• W2078019355 hasRelatedWork W2913751387 @default.
• W2078019355 hasRelatedWork W3118400354 @default.
• W2078019355 hasRelatedWork W3209745763 @default.
• W2078019355 hasRelatedWork W4306652755 @default.
• W2078019355 hasVolume "205" @default.

• next