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- W2078049001 abstract "Time-of-flight SIMS has been used to identify chemical changes caused to hexatriacontane and various hydrocarbon polymers after electrochemical treatment with nitric acid either alone or in the presence of silver ions. The spectra of polypropylene and high-density polyethylene treated in the presence of Ag2+ ions indicated the presence of hydroxyl, carbonyl and carboxyl groups. With polystyrene, attack at both the polymer backbone and the ring occurred. A styrene– butadiene– styrene (SBS) block copolymer was the most extensively modified, with preferential attack of the butadiene. Nitrate ester groups were detected in all cases but the concentration was much higher for SBS than for the other polymers. Oxidation of hexatriacontane was confirmed for the first time. In the absence of silver ions the modification was chemically similar for all polymers but to a lesser extent, except in the case of SBS. Copyright © 2000 John Wiley & Sons, Ltd." @default.
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- W2078049001 date "2000-01-01" @default.
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- W2078049001 title "A ToF-SIMS study of electrochemical pretreatments for polymers" @default.
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- W2078049001 doi "https://doi.org/10.1002/1096-9918(200009)29:9<572::aid-sia898>3.0.co;2-d" @default.
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