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- W2078052204 abstract "Synthesis and structure of two new metal phosphonate salts, as well as their IR spectra and magnetic properties are presented. Both compounds form a three-dimensional supramolecular network held together by a number of hydrogen bonds and show paramagnetic behaviour with very weak antiferromagnetic interactions through H-bonds. Two new cobalt(II) phosphonate salts, {3[Co(H 2 O) 6 ] 2 (C 12 H 18 O 9 P 3 )}·11H 2 O ( 1 ) and {[Co(H 2 O) 6 ](C 12 H 19 O 9 P 3 )}·6H 2 O ( 2 ), were obtained in crystalline form. Compound 1 crystallises in the centrosymmetric space group of the triclinic system, whereas compound 2 crystallises in the P 2 1 / n space group of the monoclinic system. The asymmetric unit of 1 consists of one and a half hexaaqua cobalt(II) ions, one phosphonic acid residue and five and a half lattice water molecules. One Co 2+ ion lies in a special position and the other one in a general position. In 1 , both independent Co 2+ cations are surrounded by water molecules forming distorted octahedral coordination geometry. The asymmetric unit of 2 consists of one hexaaqua cobalt(II) ion, phosphonic acid residue and six lattice water molecules. In crystal 2 , similarly as in crystal 1 , the environment of the Co 2+ consists of water molecules that form distorted octahedral coordination geometry. The hexaaqua cobalt(II) cations interact with phosphonate counter ions and together with the solvated water molecules they form a three-dimensional hydrogen bonding supramolecular network. Magnetic susceptibility measurements exhibit paramagnetic behaviour with very weak antiferromagnetic interactions for both compounds." @default.
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- W2078052204 date "2014-10-01" @default.
- W2078052204 modified "2023-10-18" @default.
- W2078052204 title "The synthesis, structure and magnetic properties of two cobalt phosphonate salts" @default.
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- W2078052204 doi "https://doi.org/10.1016/j.poly.2014.05.047" @default.
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