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- W2078082257 endingPage "1643" @default.
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- W2078082257 abstract "The Au(III)-catalyzed hydration of 3-alkynoates led to a practical one-step synthesis of gamma-keto esters in high yields, through a carbonyl group participation enabled by a favored 5-endodig cyclization. This mild-aqueous ethanol, room temperature, and atom-economical method has been used effectively with a wide range of substrates. Using the same conditions, a 2-alkynoate produced the corresponding beta-keto ester in high yield." @default.
- W2078082257 created "2016-06-24" @default.
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- W2078082257 date "2009-01-26" @default.
- W2078082257 modified "2023-10-18" @default.
- W2078082257 title "Efficient Synthesis of γ-Keto Esters through Neighboring Carbonyl Group-Assisted Regioselective Hydration of 3-Alkynoates" @default.
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- W2078082257 doi "https://doi.org/10.1021/jo802450n" @default.
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