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• W2078088045 abstract "The ability of the Stern equation to describe the adsorption of divalent cations to phosphatidylglycerol membranes was tested by combining 31P-NMR and electrophoretic mobility measurements. In 0.1 M sodium chloride both the 31P-NMR and the zeta potential data are well described by the Stern equation. 31P-NMR and 13C-NMR results indicate that cobalt forms inner-sphere complexes only with the phosphate group of phosphatidylglycerol molecules and that a substantial fraction of the adsorbed cobalt ions form outer-sphere complexes. Evidence is presented that suggests the alkaline earth cations also bind to phospholipids mainly by forming outer sphere complexes. Electrophoretic mobility measurements were performed with several different divalent cations. In all cases the zeta potentials in 0.1 M sodium chloride were well described by the Stern equation. The intrinsic 1 : 1 association constants (M−1) for the phosphatidylglycerol complexes decreased in the sequence: Mn2+, 11.5; Ca2+, 8.5; Ni2+, 7.5; Co2+, 6.5; Mg2+, 6.0; Ba2+, 5.5 and Sr2+, 5.0." @default.
• W2078088045 created "2016-06-24" @default.
• W2078088045 creator A5045654078 @default.
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• W2078088045 date "1981-07-01" @default.
• W2078088045 modified "2023-10-18" @default.
• W2078088045 title "The adsorption of divalent cations to phosphatidylglycerol bilayer membranes" @default.
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• W2078088045 doi "https://doi.org/10.1016/0005-2736(81)90199-1" @default.
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