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- W2078096028 abstract "Single wall carbon nanohorns (SWNHs) were fluorinated to form more attractive nanohorns that have characteristic structural and adsorptive properties. Nitrogen adsorption, XPS, and TEM studies elucidated the surface states and the morphologies of fluorinated SWNHs (F−SWNHs). The XPS results of F−SWNHs showed that the nature of C−F bonds changed from semi-ionic to covalent with an increase in the fluorination temperature. The N2 adsorption isotherm indicated that the total amount of N2 adsorption on SWNHs fluorinated at 303 and 373 K was smaller than that of pristine SWNHs. After fluorination at 473 K, nanoorder windows were produced on the sidewalls of SWNHs without a change in the shape of each horn and aggregate. Therefore, the SWNHs fluorinated at 473 K can adsorb N2 molecules on the internal surfaces of nanohorns through the nanowindows." @default.
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- W2078096028 date "2004-06-18" @default.
- W2078096028 modified "2023-10-10" @default.
- W2078096028 title "Direct Thermal Fluorination of Single Wall Carbon Nanohorns" @default.
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- W2078096028 doi "https://doi.org/10.1021/jp037912i" @default.
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