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- W2078097477 abstract "A new family of five lanthanide-organic coordination polymers incorporating multi-functional N-hetrocyclic dicarboxylate ligand, namely, [Ln2(Hdpp)2(dpp)2]n Ln=Pr(1), Eu(2), Gd(3), Dy(4), Er(5) (H2dpp=1-(3, 4-dicarboxyphenyl) pyridin-4-ol) have been fabricated successfully through solvothermal reaction of 1-(3,4-dicarboxyphenyl)-4-hydroxypyridin-1-ium chloride with trivalent lanthanide salts, and have been characterized systematically. The complexes 1–5 are isomorphous and isostructural. They all feature three dimensional (3D) frameworks based on the interconnection of 1D double chains composed of the binuclear moiety [Ln2(Hdpp)2]4+ basic carboxylate as secondary building unit (SBU). The results of magnetic analysis shows the same bridging fashion of carboxylic group in this case results in the different magnetic properties occurring within lanthanide polymers. Moreover, the Eu(III) and Dy(III) complexes display characteristic luminescence emission in the visible regions." @default.
- W2078097477 created "2016-06-24" @default.
- W2078097477 creator A5029008207 @default.
- W2078097477 creator A5033336662 @default.
- W2078097477 creator A5046675865 @default.
- W2078097477 creator A5054659468 @default.
- W2078097477 creator A5056091982 @default.
- W2078097477 creator A5061786548 @default.
- W2078097477 creator A5089174985 @default.
- W2078097477 date "2013-10-01" @default.
- W2078097477 modified "2023-10-16" @default.
- W2078097477 title "Lanthanide coordination polymers based on multi-donor ligand containing pyridine and phthalate moieties: Structures, luminescence and magnetic properties" @default.
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