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- W2078110154 abstract "Unnatural nucleosides have been explored to expand the properties and the applications of oligonucleotides. This paper briefly summarizes nucleic acid analogs in which the base is modified or replaced by an unnatural stacking group for the study of nucleic acid interactions. We also describe the nucleoside analogs of a base pair-mimic structure that we have examined. Although the base pair-mimic nucleosides possess a simplified stacking moiety of a phenyl or naphthyl group, they can be used as a structural analog of Watson-Crick base pairs. Remarkably, they can adopt two different conformations responding to their interaction energies, and one of them is the stacking conformation of the nonpolar aromatic group causing the site-selective flipping of the opposite base in a DNA double helix. The base pair-mimic nucleosides can be used to study the mechanism responsible for the base stacking and the flipping of bases out of a nucleic acid duplex." @default.
- W2078110154 created "2016-06-24" @default.
- W2078110154 creator A5041513545 @default.
- W2078110154 creator A5063543498 @default.
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- W2078110154 date "2011-01-01" @default.
- W2078110154 modified "2023-10-17" @default.
- W2078110154 title "Use of Nucleic Acid Analogs for the Study of Nucleic Acid Interactions" @default.
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- W2078110154 doi "https://doi.org/10.4061/2011/967098" @default.
- W2078110154 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3142669" @default.
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