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- W2078111234 abstract "Abstract To summarize, it is important to recognize that (1) the major objective of our GCA paper (Faust et al., 1995) was on the development of 27Al NMR spectroscopy for characterizing mononuclear Al (III) species at concentrations of geochemical relevance; (2) Ohman has only minor comments related to this major objective; and (3) these comments are rebutted above in section 1. We appreciate Ohman's suggestion to consider adsorption of Al(III) onto the Teflon NMR sample bottle. Indeed, a small but significant percentage of Al(III) was adsorbed to the surfaces of the Teflon NMR sample bottle under the conditions of our experiments, partially accounting for the decrease in total concentration of mononuclear Al(III) species that was detected by 27Al NMR spectroscopy. As noted above in section 1, since the 27Al NMR spectroscopic parameters are not affected by decreases in total concentration of mononuclear Al(III) species, this does not affect the interpretation of the 27Al NMR chemical shifts or linewidths." @default.
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- W2078111234 date "1997-08-01" @default.
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- W2078111234 title "Reply to the comment by L.-O. Öhman on “speciation of aqueous mononuclear” Al(III)-hydroxo and other Al(III) complexes at concentrations of geochemical relevance by aluminum-27 nuclear magnetic resonance spectroscopy" @default.
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