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- W2078116327 abstract "Molecular dynamics calculations have been used to investigate the behavior of overlayers of water or n-alkane fluids on solid surfaces formed from “self-assembled” monolayers of long-chain hydrocarbons. A microscopic analog of the wetting contact angle is used to measure the surface wetting characteristics. On a nonpolar surface, formed by close packed chains having -CH 3 tailgroups, the water molecules aggregate to form a compact droplet. The calculated contact angle of the droplet is similar to experimental values for macroscopic water droplets. Contrary to intuition, the overlayers of hexadecane or decane form droplets with smaller contact angles on the same surface. However, the calculated contact angles are again in reasonable accord with experimental values." @default.
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- W2078116327 date "1995-03-01" @default.
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- W2078116327 title "Molecular dynamics studies of microscopic wetting phenomena on self-assembled monolayers" @default.
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- W2078116327 doi "https://doi.org/10.1016/0927-0256(95)00006-c" @default.
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