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• W2078118512 startingPage "935" @default.
• W2078118512 abstract "The preparation of the C1-C11 subunit of phoslactomycins, and a formal synthesis of phoslactomycin B, were achieved by a convergent strategy involving the chelation-controlled addition of an alkynyl Grignard reagent to an alpha-alkoxy ketone. Catalytic enantioselective reductions of acetylenic ketones and a [2,3]-Wittig rearrangement were utilized as key steps to control the configuration of the C4, C5, and C9 stereocenters." @default.
• W2078118512 created "2016-06-24" @default.
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• W2078118512 date "2009-01-26" @default.
• W2078118512 modified "2023-10-18" @default.
• W2078118512 title "A Convergent Approach toward the C1−C11 Subunit of Phoslactomycins and Formal Synthesis of Phoslactomycin B" @default.
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• W2078118512 doi "https://doi.org/10.1021/ol8029142" @default.
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