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- W2078119617 abstract "The effects of a thermal gradient on the dynamical behavior of nanoparticles dispersed in a polymer matrix were studied using X-ray photon correlation spectroscopy. Polystyrene (PS)-grafted silica nanoparticles (SiNPs-PS), which are nanoparticles dispersed in a PS matrix controlled at temperatures above the glass transition temperature, were used in this study. Anisotropic motions of the SiNPs-PS were observed when the sample was kept in a conventional capillary tube, whereas isotropic motion was observed when the sample was kept in a newly designed cell with a low thermal flow, demonstrating the importance of the thermal gradient on the dynamical behavior of the SiNPs-PS. The effects of thermal gradient on dynamical behavior of nanoparticles dispersed in polymer matrix were studied by X-ray photon correlation spectroscopy. Anisotropic motions of nanoparticles were observed when the sample was kept in a cell using a capillary tube covered with copper block. As the same experiment using another cell without such thermal gradient clearly demonstrated that even the small thermal gradient around the probe windows caused the anisotropic dynamical behavior." @default.
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- W2078119617 date "2012-11-21" @default.
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- W2078119617 title "Thermal gradient effect on the dynamical behavior of nanoparticles observed using X-ray photon correlation spectroscopy" @default.
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- W2078119617 doi "https://doi.org/10.1038/pj.2012.193" @default.
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