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- W2078127956 abstract "An analytical group solution model (AGSM) previously developed for the prediction of heats of mixing has been applied to ternary group, ternary component mixtures. A simple temperature dependence is proposed for the group interaction parameters. Temperature independent coefficients were obtained in the temperature range 15 to 35°C for mixtures containing CH2, OH and Cl groups. These coefficients allow the prediction of heat of mixing for binary or ternary mixtures containing alcohols, chloroalkanes and alkanes. Heats of mixing for the following systems are reported: 1-chlorobutane and 2-chlorobutane with both n-hexane and n-octanol at 35°C; n-octanol — n-hexane at 25 and 35°C; and three chords of the ternary system 1-chlorobutane — n-octanol — n-hexane at 25 and 35°C. On a appliqué à des mélanges de groupes ternaires et de composants ternaires un modèle analytique de solutions pour groupes (AGSM). On propose une simple dépendance de la température pour les paramètres d'interaction des groupes. On a obtenu des coefficients indépendants de la température, dans le domaine de températures comprises entre 15°C et 35°C, pour le cas de mélanges contenant les groupes CH3, OH et Cl. Lesdits coefficients permettent de prévoir les chaleurs de mélange dans le cas de mélanges binaires ou ternaires contenant des alcools, des chloroalcanes et des alcanes. On rapporte les chaleurs de mélange pour les systèmes suivants: (a) 1-chlorobutane et 2-chlorobutane avec l'hexane normal et l'octanol normal à 35°C; (b) l'octanol normal et l'hexane normal à 25°C et 25°C; (c) 3 cordes du système ternaire l-chlorobutane-octanol normal-hexane normal à 25°C et 35°C." @default.
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- W2078127956 date "1978-06-01" @default.
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- W2078127956 title "Prediction of heats of mixing of liquid mixtures containing alkane, chloroalkane and alcohol by an analytical group solution model" @default.
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- W2078127956 doi "https://doi.org/10.1002/cjce.5450560314" @default.
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