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- W2078128440 abstract "Abstract It was revealed by thorough study of the T·T ∗ (C 1 ) ↔ T ∗ ·T (C 1 ) tautomerisation via the synchronous concerted double proton transfer (DPT) through the TS (C 2v ) that the T·T ∗ /T ∗ ·T H-bonded mismatch is dynamically stable non-planar complex with a lifetime 1.6 × 10 −10 s. The 5 key points were firstly detected and completely investigated along the intrinsic reaction coordinate of the DPT tautomerisation. The reported data allow us to suggest that the T ∗ mutagenic tautomer of the thymine (T) is shared with approximately equal probability between two DNA strands during the dissociation of the mispair by DNA polymerase." @default.
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- W2078128440 date "2014-01-01" @default.
- W2078128440 modified "2023-10-15" @default.
- W2078128440 title "Structural, energetic and tautomeric properties of the T·T∗/T∗·T DNA mismatch involving mutagenic tautomer of thymine: A QM and QTAIM insight" @default.
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- W2078128440 doi "https://doi.org/10.1016/j.cplett.2013.12.034" @default.
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