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• W2078128947 startingPage "1726" @default.
• W2078128947 abstract "Three types of polypropylene, namely propylene homopolymer (HPP), block copolymer of propylene with ethylene (CPP-B) and random copolymer of propylene with ethylene (CPP-R), were melted and isothermally crystallized in a self-designed vessel under supercritical carbon dioxide (Sc-CO2) atmosphere. The melting behavior and crystalline forms of crystallized samples were investigated using differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WAXD). The results showed that the presence of Sc-CO2 could improve the crystallinity for all three polypropylenes, and the promoting effect was more obivious with increasing CO2 pressure. In addition, it was observed that γ-crystals could be obtained in the CPP-B and CPP-R samples crystallized under Sc-CO2, while no γ-crystals were formed in HPP under the given conditions. The relative content of γ-crystals obtained in CPP-R samples was much higher than that of CPP-B, and 100% γ-phase could be formed in the CPP-R sample when subjected to 14 MPa Sc-CO2." @default.
• W2078128947 created "2016-06-24" @default.
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• W2078128947 date "2014-10-15" @default.
• W2078128947 modified "2023-10-16" @default.
• W2078128947 title "Comparison Study on CO₂-Promoted Crystallization and Melting Behavior of Polypropylene: Homopolymer and Copolymers" @default.
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• W2078128947 doi "https://doi.org/10.1080/00222348.2014.966892" @default.
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