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• W2078145270 abstract "The effect of different polymerization start up methods in slurry phase polyethylene production with high activity Ziegler/Natta-catalysts was studied. From the presented results it can be concluded that the method of polymerization start up has a strong effect on development of polymerization activity as well as on polymer powder morphology. This fact should be taken into account when comparing results from different literature sources. The observed differences seem likely to be caused by differences in the rate of diffusion of cocatalyst molecules to potential active sites in the interior of the catalyst precursor. The development of cobweb structures in polymer particles [15], often observed in slurry phase poly- ethylene polymerization can also be explained in terms of cocatalyst diffusion inside the catalyst precursor particles." @default.
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• W2078145270 date "1991-11-01" @default.
• W2078145270 modified "2023-10-18" @default.
• W2078145270 title "Ziegler/Natta catalysts in particle form ethylene polymerization: The effect of polymerization start-up on catalyst activity and morphology of the produced polymer" @default.
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• W2078145270 doi "https://doi.org/10.1016/0920-5861(91)87005-8" @default.
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