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- W2078145387 abstract "Control of the regioselective thiocarbonylation of terminal acetylenes 1a–e with arylthiols 2a,b was successfully achieved by using Pd(OAc)2 and 1,4-bis(diphenylphosphino)butane (dppb), or 1,3-bis(diphenylphosphino)propane (dppp), as catalysts. The formation of the thioesters 3 or 4 depends mainly on the type of ligand (dppp or dppb) and the solvent (THF or CH2Cl2) under CO/H+ or syngas mixture." @default.
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- W2078145387 date "2001-02-01" @default.
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- W2078145387 title "Regioselective control of the thiocarbonylation of terminal acetylenes with arylthiols catalyzed by Pd(II) and diphosphine ligands" @default.
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