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- W2078156915 abstract "Rearrangement of Azidomalonic EstersDimethyl azido[6-(methoxycarbonyl)-2-oxo-2H-pyran-4-ylmethyl]malonate (4) is photolyzed under loss of nitrogen and rearrangement of one methoxycarbonyl group to form the mixture of Z und E isomers of the α,β-unsaturated amino acid esters 8 and 9. On photolysis of isopropyl- and isobutylazidomalonates 10 migration of the alkyl group is observed exclusively. The (alkylimino)malonates 14 so formed have been hydrogenated and hydrolyzed to give the N-alkylglycine derivatives 16." @default.
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- W2078156915 date "1986-11-12" @default.
- W2078156915 modified "2023-10-17" @default.
- W2078156915 title "Zur Umlagerung von Azidomalonestern" @default.
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- W2078156915 doi "https://doi.org/10.1002/jlac.198619861118" @default.
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