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• W2078162315 startingPage "7698" @default.
• W2078162315 abstract "Transition metal-catalyzed acyloxy migration of propargylic esters offers versatile entries to allene and vinyl carbene intermediates for various fascinating subsequent transformations. Most π-acidic metals (e.g. gold and platinum) are capable of facilitating these acyloxy migration events. However, very few of these processes involve redox chemistry, which are well-known for most other transition metals such as rhodium. The coupling of acyloxy migration of propargylic esters with oxidative addition, migratory insertion, and reductive elimination may lead to ample new opportunities for the design of new reactions. This tutorial review summarizes recent developments in Rh-catalyzed 1,3- and 1,2-acyloxy migration of propargylic esters in a number of cycloaddition reactions. Related Au- and Pt-catalyzed cycloadditions involving acyloxy migration are also discussed." @default.
• W2078162315 created "2016-06-24" @default.
• W2078162315 creator A5036313933 @default.
• W2078162315 creator A5050414147 @default.
• W2078162315 creator A5059269006 @default.
• W2078162315 creator A5087354808 @default.
• W2078162315 date "2012-01-01" @default.
• W2078162315 modified "2023-10-18" @default.
• W2078162315 title "Rhodium-catalyzed acyloxy migration of propargylic esters in cycloadditions, inspiration from the recent “gold rush”" @default.
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• W2078162315 doi "https://doi.org/10.1039/c2cs35235d" @default.
• W2078162315 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/3491182" @default.
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• W2078162315 hasPublicationYear "2012" @default.
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