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• W2078163312 startingPage "5740" @default.
• W2078163312 abstract "Spectroscopic (Raman, NMR, impedance spectroscopy), and thermal [differential scanning calorimetry (DSC)] techniques have been used to study the solvation mechanism of lithium ions in ethylene carbonate (EC)–propylene carbonate (PC) concentrated solutions. For values of N=[Li+]/[EC+PC]⩽0.2 all the cations are solvated by ∼4 solvent molecules and interaction chiefly takes place between Li+ and the ring oxygens. For N&gt;0.2 a part of Li+ ions begins to form complexes with two solvent molecules (sandwich configuration). At N≅0.5 nearly all cations are complexed, and a crystalline compound is formed at room temperature. For higher values of N a reassociation of the salt takes place." @default.
• W2078163312 created "2016-06-24" @default.
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• W2078163312 date "1997-10-15" @default.
• W2078163312 modified "2023-09-26" @default.
• W2078163312 title "Li + solvation in ethylene carbonate–propylene carbonate concentrated solutions: A comprehensive model" @default.
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• W2078163312 doi "https://doi.org/10.1063/1.474334" @default.
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