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- W2078164421 abstract "Abstract An analysis of the internal rotation fine structure for the rotational transitions of hexa-deutero dimethyl selenide in the first excited torsional states is presented in terms of a molecular model with two degrees of freedom for the internal rotation or torsion of the two tops in addition to the three degrees of freedom for the overall rotation. By a least squares fit of the multiplet splittings of ten transitions in the v n =1 1 and nine transitions in the ṽ n =1 2 excited torsional states, the following parameters have been obtained: F 3 =1493±9 cal mol -1 ; ϑ=50°1′±7′ V 12 ′=28.4±0.3 cal mol -1 . The splitting of the fine structure components could be nicely fitted, but not their absolute frequencies and the seperation between the two multiplets." @default.
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- W2078164421 date "1976-11-01" @default.
- W2078164421 modified "2023-09-27" @default.
- W2078164421 title "Top-Top Interaction in Hexa-Deutero Dimethyl Selenide from the Microwave Spectrum in the First Excited Torsional States" @default.
- W2078164421 doi "https://doi.org/10.1515/zna-1976-1122" @default.
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