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- W2078164502 abstract "Methylcis-9,cis-15-octadecadienoate was partially deuterated with nickel catalyst, and the product was separated into saturate, monoene and diene fractions. Monoenes were separated intotrans andcis fractions, and dienes intotrans,trans, cis,trans andcis,cis fractions. Monoene isomers with double bonds at the 9 and 15 positions predominated in bothcis- andtrans-monoene fractions. Considerable amounts of isomers with double bonds situated on either side of the original 9 and 15 positions were found in thetrans-monoene fraction. Diene was extensively isomerized to positional and geometrical isomers, and deuterium was incorporated into these isomers. Double bond migration was greatest intrans,trans-dienes and smallest incis,cis-dienes. The amount of deuterium in the dienes was proportional to the extent of isomerization experienced by the dienes." @default.
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- W2078164502 date "1973-08-01" @default.
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- W2078164502 title "Deuteration of methylcis-9,cis-15-octadecadienoate with nickel catalyst" @default.
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- W2078164502 doi "https://doi.org/10.1007/bf02641362" @default.
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