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- W2078165612 abstract "Abstract The photostimulated reaction of methyl 2,5‐dichloro benzoate ( 1 ) or methyl 3,6‐dichloro‐2‐methoxy benzoate ( 7 ) with − SnMe 3 ions give good yields of the disubstitution products by the S RN 1 mechanism in liquid ammonia. Conversely, in dark conditions, substrate 1 reacts with − SnMe 3 ions to afford the mono‐substitution products by the S RN 1 mechanism. On the other hand, substrate 7 reacts with − SnMe 3 ions in dark conditions to give mono‐reduced product probably by a halogen metal exchange reaction. In addition, the photostimulated reaction of 2‐chloro‐ N 4 ‐ethyl‐ N 6 ‐isopropyl‐1,3,5‐triazin‐4,6‐diamine (Atrazine, 11 ) with − SnMe 3 ions affords the reduced and substitution products in liquid ammonia‐DMSO as co‐solvent. Copyright © 2006 John Wiley & Sons, Ltd." @default.
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- W2078165612 date "2006-11-03" @default.
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- W2078165612 title "Trimethylstannylation of mono‐ and dichloroarenes by the S<sub>RN</sub>1 mechanism in liquid ammonia" @default.
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