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- W2078165820 startingPage "1479" @default.
- W2078165820 abstract "Reaction of Cu(NO 3 ) 2 , NH 4 OH, phen (1,10-phenanthroline) and KCN in the molar ratio 1:40:2:2 in water-ethanol solution gives a new mixed-valence complex of composition Cu 2 (phen) 3 (CN) 3.5 H 2 O. X-ray structure analysis reveals the composition [Cu II (phen) 2 (CN)] + [Cu I (phen)(CN) 2 ] - .5H 2 O with trigonal-bipyramidal and tetrahedral coordination for the divalent and univalent Cu atoms, respectively. The structure is built up of hydrated clusters comprising two formula units; the principal interactions within the cluster are hydrogen bonds between the water molecules and complex cations and anions" @default.
- W2078165820 created "2016-06-24" @default.
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- W2078165820 date "1993-08-15" @default.
- W2078165820 modified "2023-10-18" @default.
- W2078165820 title "Mixed-valence CuI–CuII complexes. Structure of cyanobis(1,10-phenanthroline)copper(II) bis(cyano)(1,10-phenanthroline)cuprate(I) pentahydrate" @default.
- W2078165820 doi "https://doi.org/10.1107/s0108270193001775" @default.
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