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- W2078166318 abstract "Die Struktur eines früher als 1 angesehenen Orthophosphorsäureesters erwies sich als einkernige Phosphorverbindung, die in Abhängigkeit vom Lösungsmittel in penta-(4) bzw. hexacoordinierter (5) Form vorliegt. Das Triäthylammoniumsalz 8 dieser ersten hexacoordinierten Phosphorsäure mit sechs PO-Bindungen 5 ist überraschend leicht aus tri-, tetra- und pentacoordinierten Verbindungen der phosphorigen bzw. Phosphorsäure oder Thiophosphorsäure zugänglich. Derivatives of o-Phenylenephosphate. XV. Synthesis of Tris-(o-phenylenedioxy)-phosphorate(V) The structure of an orthophosphate which had been supposed earlier to represent type 1, has been proven to be a compound having only one P-nucleus in the molecule, with a penta(4) resp. hexacoordinated (5) structure depending on the solvent. The triethyl-ammonium salt 8 of this first example of a hexacoordinated phosphoric acid with 6 PO-bonds (5) is formed simply from tri- als well as from tetra- and pentacoordinated derivatives of phosphorous resp. phosphoric or thiophosphoric acid." @default.
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- W2078166318 date "1977-01-01" @default.
- W2078166318 modified "2023-10-05" @default.
- W2078166318 title "Derivate des Phosphorsäure-o-phenylenesters. XV [1]. Synthese von Tris-(o-phenylendioxy)-phosphorat(V)" @default.
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- W2078166318 doi "https://doi.org/10.1002/prac.19773190203" @default.
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