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- W2078166939 endingPage "6779" @default.
- W2078166939 startingPage "6767" @default.
- W2078166939 abstract "The electronic excitation of chemisorbed Cs atoms through the coherent photoinduced charge transfer from the Cu(111) surface turns on repulsive forces that initiate the dissociative wave packet motion. Due to unusually slow electronic relaxation, with the interferometric time-resolved two-photon photoemission technique it is possible to follow the characteristic change in the surface electronic structure due to the ensuing nuclear dynamics for ∼200 fs after excitation. This direct observation of the incipient bond breaking process on a metal surface provides information on a series of complex electronic and nuclear events that previously could be gleaned only through analysis of the reaction products. The metal band structure, the polarizability of the Cs atom, and the mechanical properties of the surface strongly influence the electronic and nuclear relaxation, and therefore, the reaction efficiency. The importance of time-resolved methods in studying of surface reactions is underscored by significant deviations in the electronic and nuclear dynamics of Cs/Cu(111) from the standard models for surface photochemistry." @default.
- W2078166939 created "2016-06-24" @default.
- W2078166939 creator A5001002767 @default.
- W2078166939 creator A5033344883 @default.
- W2078166939 creator A5038175566 @default.
- W2078166939 creator A5042633411 @default.
- W2078166939 date "2001-06-27" @default.
- W2078166939 modified "2023-10-11" @default.
- W2078166939 title "Surface Femtochemistry: Frustrated Desorption of Alkali Atoms from Noble Metals" @default.
- W2078166939 cites W1548464798 @default.
- W2078166939 cites W1964069776 @default.
- W2078166939 cites W1965902676 @default.
- W2078166939 cites W1966820683 @default.
- W2078166939 cites W1967191375 @default.
- W2078166939 cites W1969745247 @default.
- W2078166939 cites W1970917170 @default.
- W2078166939 cites W1971185255 @default.
- W2078166939 cites W1974069169 @default.
- W2078166939 cites W1976444423 @default.
- W2078166939 cites W1977088104 @default.
- W2078166939 cites W1977894354 @default.
- W2078166939 cites W1978199358 @default.
- W2078166939 cites W1978686665 @default.
- W2078166939 cites W1978697091 @default.
- W2078166939 cites W1979105464 @default.
- W2078166939 cites W1979770453 @default.
- W2078166939 cites W1981640305 @default.
- W2078166939 cites W1983603123 @default.
- W2078166939 cites W1984316743 @default.
- W2078166939 cites W1984710660 @default.
- W2078166939 cites W1985014868 @default.
- W2078166939 cites W1986892968 @default.
- W2078166939 cites W1988133899 @default.
- W2078166939 cites W1989690459 @default.
- W2078166939 cites W1989774021 @default.
- W2078166939 cites W1991427367 @default.
- W2078166939 cites W1993930460 @default.
- W2078166939 cites W1994275876 @default.
- W2078166939 cites W1995352868 @default.
- W2078166939 cites W1996618394 @default.
- W2078166939 cites W1997487974 @default.
- W2078166939 cites W1998253725 @default.
- W2078166939 cites W1999172376 @default.
- W2078166939 cites W1999394779 @default.
- W2078166939 cites W2002108827 @default.
- W2078166939 cites W2003177179 @default.
- W2078166939 cites W2003540632 @default.
- W2078166939 cites W2003790247 @default.
- W2078166939 cites W2007203783 @default.
- W2078166939 cites W2007317382 @default.
- W2078166939 cites W2012024869 @default.
- W2078166939 cites W2016346220 @default.
- W2078166939 cites W2016937812 @default.
- W2078166939 cites W2017281865 @default.
- W2078166939 cites W2018432014 @default.
- W2078166939 cites W2019676191 @default.
- W2078166939 cites W2019691859 @default.
- W2078166939 cites W2020252677 @default.
- W2078166939 cites W2020703105 @default.
- W2078166939 cites W2025168551 @default.
- W2078166939 cites W2026937917 @default.
- W2078166939 cites W2028404816 @default.
- W2078166939 cites W2029379110 @default.
- W2078166939 cites W2029567090 @default.
- W2078166939 cites W2029761950 @default.
- W2078166939 cites W2030591142 @default.
- W2078166939 cites W2030992196 @default.
- W2078166939 cites W2031285423 @default.
- W2078166939 cites W2032724800 @default.
- W2078166939 cites W2033079093 @default.
- W2078166939 cites W2035586362 @default.
- W2078166939 cites W2039420842 @default.
- W2078166939 cites W2039549038 @default.
- W2078166939 cites W2039986333 @default.
- W2078166939 cites W2046468756 @default.
- W2078166939 cites W2046829719 @default.
- W2078166939 cites W2048487844 @default.
- W2078166939 cites W2048740373 @default.
- W2078166939 cites W2049904901 @default.
- W2078166939 cites W2050129921 @default.
- W2078166939 cites W2050718769 @default.
- W2078166939 cites W2051165098 @default.
- W2078166939 cites W2053290544 @default.
- W2078166939 cites W2054689416 @default.
- W2078166939 cites W2054957755 @default.
- W2078166939 cites W2056168767 @default.
- W2078166939 cites W2061876455 @default.
- W2078166939 cites W2062947143 @default.
- W2078166939 cites W2064727842 @default.
- W2078166939 cites W2065574318 @default.
- W2078166939 cites W2065981637 @default.
- W2078166939 cites W2066492928 @default.
- W2078166939 cites W2069204392 @default.
- W2078166939 cites W2069649348 @default.
- W2078166939 cites W2069818376 @default.
- W2078166939 cites W2070260948 @default.
- W2078166939 cites W2073353982 @default.
- W2078166939 cites W2073563825 @default.