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W2078167872 abstract "Three new multidimensional coordination polymers have been constructed from the reaction of AgX, where X = OTf-, BF4-, or tfa-, with the novel phosphonite PhP(3-OCH2C5H4N)2, PCP-32, 1. It is seen that regardless of the ratio of reactants mixed, polymeric growth of the compounds always reveals a ligand-to-metal ratio of 1:2 for PCP-32AgOTf, 2, 1:1 for PCP-32AgBF4, 3, and 1:2 for PCP-32Ag(tfa), 4. The coordination number, metal environment, ligand conformation, and polymer dimensionality are found to vary greatly from 2 to 4 and are dependent upon the anion present. Coordination numbers from 2 to 4, representing linear, trigonal, and distorted tetrahedral environments are displayed. PCP-32AgOTf polymerizes as a linear chain containing both two- and four-coordinate silvers, PCP-32AgBF4 repeats a single trigonal motif throughout its structure, and PCP-32Ag(tfa) shows two unique distorted tetrahedral silver centers. Ligand flexibility allows for cross-ligand Ag−Ag distances to range from 3.1918(8) to 14.015(2) Å. The coordination polymers have been characterized by elemental analysis, variable-temperature multinuclear NMR spectroscopy, single-crystal X-ray diffraction, and fluorometric studies." @default.
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W2078167872 date "2005-01-11" @default.
W2078167872 modified "2023-09-23" @default.
W2078167872 title "Anion-Dependent Silver(I) Coordination Polymers of the Tridentate Pyridylphosphonite: PPh(3-OCH2C5H4N)2" @default.
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W2078167872 doi "https://doi.org/10.1021/ic0486365" @default.
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