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- W2078169860 endingPage "1697" @default.
- W2078169860 startingPage "1693" @default.
- W2078169860 abstract "The simple expression 〈v'ensuremath{Vert}fensuremath{Delta}${mathit{U}}^{mathit{n}}$gensuremath{Vert}v'〉 is offered tg are some operators which couple the vibrational levels v' and v'' of two interacting electronic states and ensuremath{Delta}U=U'-U'' is the difference of the corresponding internuclear potentials. The rigorous quantum proofs as well as semiclassical justification of this formula are presented and its absolute accuracy is estimated in a closed functional form. Invariant properties and spectroscopic applications of the sum rule, including the evaluation of lifetimes, fine-structure (ensuremath{Lambda}-doubling) constants, and Land'e factors, are discussed." @default.
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- W2078169860 date "1994-03-01" @default.
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- W2078169860 title "Approximate sum rule for diatomic vibronic states" @default.
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- W2078169860 doi "https://doi.org/10.1103/physreva.49.1693" @default.
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