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- W2078171092 abstract "Effects of the hydrostatic pressure on the magnetic and structural properties are investigated in a charge-transfer material, $mathrm{Cs}[mathrm{Co}{(3text{ensuremath{-}}mathrm{C}mathrm{N}mathrm{py})}_{2}][mathrm{W}{(mathrm{C}mathrm{N})}_{8}]{mathrm{H}}_{2}mathrm{O}$ $(mathrm{C}mathrm{N}mathrm{py}=text{cyanopyridine})$, with two-dimensional Co-W network bridged by CN anions. We have found that the compound shows a pressure-induced charge-transfer (CT) transition at $0.5phantom{rule{0.3em}{0ex}}mathrm{GPa}$ at room temperature, accompanied by a remarkable color change from transparent red to green. The upper critical temperature $({T}_{mathrm{CT},text{up}})$ for the CT transition increases at a huge rate of $250phantom{rule{0.3em}{0ex}}mathrm{K}∕mathrm{GPa}$ under pressures, reflecting the concomitant significant volume change $(ensuremath{Delta}V∕V=0.08)$." @default.
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- W2078171092 title "Pressure-temperature phase diagram for charge-transfer transition in<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:mi mathvariant=normal>Cs</mml:mi><mml:mrow><mml:mo>[</mml:mo><mml:mi mathvariant=normal>Co</mml:mi><mml:msub><mml:mrow><mml:mo>(</mml:mo><mml:mn>3</mml:mn><mml:mtext>−</mml:mtext><mml:mi mathvariant=normal>C</mml:mi><mml:mi mathvariant=normal>N</mml:mi><mml:mi>py</mml:mi><mml:mo>)</mml:mo></mml:mrow><mml:mn>2</mml:mn></mml:msub><mml…" @default.
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- W2078171092 doi "https://doi.org/10.1103/physrevb.77.012101" @default.
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