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• W2078173750 endingPage "1199" @default.
• W2078173750 startingPage "1196" @default.
• W2078173750 abstract "The van der Waals energy between an atom and a metallic cylindrical surface is calculated in the limit that the radius of the cylinder approaches zero. It is found that in this limiting case the van der Waals energy is greatly enhanced over that of the planar surface case. The calculated enhancement factor is 4.7 for the atom-surface distance at 3 a.u. and is 4.2 at 4 a.u. We propose that this enhancement effect is the general origin of the numerous experimental observations of the enhanced reactivities at the edges of stepped surfaces of some transition metals. The theory gives a ${ensuremath{rho}}^{mathrm{ensuremath{-}}3}$ dependence for large ensuremath{rho} rather than a ${ensuremath{rho}}^{mathrm{ensuremath{-}}5}$ dependence, which holds for nonconducting linear substrates only." @default.
• W2078173750 created "2016-06-24" @default.
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• W2078173750 date "1990-01-15" @default.
• W2078173750 modified "2023-10-18" @default.
• W2078173750 title "Enhancement of the van der Waals energy between an atom and a cylindrical surface: Application to the edges of stepped surfaces" @default.
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• W2078173750 doi "https://doi.org/10.1103/physrevb.41.1196" @default.
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