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- W2078175691 abstract "Abstract Simultaneous DTA-TG, TPD-GC, BET specific surface area and FT-IR measurements have been carried out on Ln-montmorillonites (Ln La, Nd, Gd, Ho or Yb) in order to study the effect of air-heating at 300°C on LnIII fixation and subsequent thermal dehydration. In the unheated samples, the hydration shell of the exchangeable 4f ions contains an average number of H2O molecules which ranges from 20 (La) to 12 (Yb). This decrease can be ascribed to partial hydrolysis of interlamellar cations, which increases for all the samples on heating at 300°C. Deprotonation of the montmorillonites by reaction of their structural OH groups with the interlamellar 4f hydroxides is suggested." @default.
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- W2078175691 date "1990-07-01" @default.
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- W2078175691 title "Effect of pre-heating on the thermal dehydration of lanthanide montmorillonites" @default.
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- W2078175691 doi "https://doi.org/10.1016/0040-6031(90)80450-d" @default.
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