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• W2078177060 endingPage "9383" @default.
• W2078177060 startingPage "9372" @default.
• W2078177060 abstract "Abstract Facile synthetic routes have been developed that provide access to cationic and anionic water‐soluble polyferrocenylsilane (PFS) polyelectrolytes with controlled molecular weight and narrow polydispersity. Living photolytic ring‐opening polymerization of amino‐functionalized [1]ferrocenophane (fc) monomers [fcSiMe{CCCH 2 N(SiMe 2 CH 2 ) 2 }] ( 3 ), [fcSi{CCCH 2 N(SiMe 2 CH 2 ) 2 } 2 ] ( 10 ), [fcSiMe(CCCH 2 NMe 2 )] ( 14 ), and [fcSiMe( p ‐C 6 H 4 CH 2 NMe 2 )] ( 20 ) yielded the corresponding polyferrocenylsilanes [(fcSiMe{CCCH 2 N(SiMe 2 CH 2 ) 2 }) n ]( 5 ), [(fcSi{CCCH 2 N(SiMe 2 CH 2 ) 2 } 2 ) n ] ( 11 ), [{fcSiMe(CCCH 2 NMe 2 )} n ] ( 15 ), and [{fcSiMe( p ‐C 6 H 4 CH 2 NMe 2 )} n ] ( 21 ) with controlled architectures. Further derivatization of 5 , 15 , and 21 generated water‐soluble polyelectrolytes [(fcSiMe{CCCH 2 N(CH 2 CH 2 CH 2 SO 3 Na) 2 }) n ] ( 6 ), [{fcSiMe(CCCH 2 NMe 3 OSO 3 Me)} n ] ( 7 ), and [{fcSiMe( p ‐C 6 H 4 CH 2 NMe 3 OSO 3 Me)} n ] ( 22 ), respectively. The polyelectrolytes were readily soluble in water and NaCl aqueous solutions, with 6 and 22 exhibiting long‐term stability in aqueous media. The PFS materials 6 and 22 , have been utilized in the layer‐by‐layer (LbL) self‐assembly of electrostatic superlattices. Our preliminary studies have indicated that films made from controlled low molecular‐weight PFSs possess a considerably thinner bilayer thickness and higher refractive index than those made from PFSs that have an uncontrolled high molecular‐weight. These results suggest that the structure and optical properties of LbL ultra‐thin films can be tuned by varying polyelectrolyte chain length. The water‐soluble low molecular weight PFSs are also useful materials for a range of applications including LbL self‐assembly in highly confined spaces." @default.
• W2078177060 created "2016-06-24" @default.
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• W2078177060 date "2007-11-08" @default.
• W2078177060 modified "2023-10-17" @default.
• W2078177060 title "Living Photolytic Ring-Opening Polymerization of Amino-Functionalized [1]Ferrocenophanes: Synthesis and Layer-by-Layer Self-Assembly of Well-Defined Water-Soluble Polyferrocenylsilane Polyelectrolytes" @default.
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• W2078177060 doi "https://doi.org/10.1002/chem.200700580" @default.
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