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- W2078177557 startingPage "755" @default.
- W2078177557 abstract "The heat capacity of the metallic, ferromagnetic compound $ensuremath{beta}ensuremath{-}mathrm{U}{mathrm{H}}_{3}$ was determined from 1.4 to 23 ifmmode^circelsetextdegreefi{}K. An attempt was made to fit the data at the lowest temperatures by an equation of the form ${C}_{p}=ensuremath{gamma}T+A{T}^{3}+B{T}^{frac{3}{2}}$, where $ensuremath{gamma}T$ is the contribution of the conduction electrons, $A{T}^{3}$ is the lattice contribution, and $B{T}^{frac{3}{2}}$ is the magnetic contribution. The coefficient $ensuremath{gamma}$ is 29ifmmodepmelsetextpmfi{}1 mJ ifmmode^circelsetextdegreefi{}${mathrm{K}}^{ensuremath{-}2}$ ${mathrm{mole}}^{ensuremath{-}1}$. Because of uncertainty in the magnetic contribution, no reliable estimate of $A$ or of the Debye $ensuremath{Theta}$ could be made. The thermodynamic functions ${S}^{ensuremath{circ}}$, $frac{({H}^{ensuremath{circ}}ensuremath{-}H_{0}^{}{}_{}{}^{ensuremath{circ}})}{T}$ and $frac{({G}^{ensuremath{circ}}ensuremath{-}H_{0}^{}{}_{}{}^{ensuremath{circ}})}{T}$ were reevaluated as 63.67ifmmodepmelsetextpmfi{}0.13, 30.24ifmmodepmelsetextpmfi{}0.06, and -33.43ifmmodepmelsetextpmfi{}0.07 J ${(mathrm{ifmmode^circelsetextdegreefi{}}mathrm{K}phantom{rule{0ex}{0ex}}mathrm{m}mathrm{o}mathrm{l}mathrm{e})}^{ensuremath{-}1}$, respectively, at 298.15 ifmmode^circelsetextdegreefi{}K." @default.
- W2078177557 created "2016-06-24" @default.
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- W2078177557 date "1967-12-10" @default.
- W2078177557 modified "2023-09-25" @default.
- W2078177557 title "β-Uranium Hydride: Heat Capacities from 1.4 to 23 °K and Some Derived Properties" @default.
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- W2078177557 doi "https://doi.org/10.1103/physrev.164.755" @default.
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