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- W2078183713 abstract "Three porous lanthanide-organic frameworks, [Ln(4)(OH)(4)(3-SBA)(4)(H(2)O)(4)].nH(2)O [Ln = Eu(III) (1), n = 10; Gd(III) (2), n = 10; Tb(III) (3), n = 8; 3-SBA = 3-sulfobenzoate], have been prepared by a hydrothermal synthesis method. They are isomorphous and crystallize in a tetragonal system with space group P 42(1)c. The structure can be considered to be built up by cubanelike [Ln(4)(OH)(4)](8+) secondary building units, which are further connected by 3-SBA to form a 3D coordination framework with 1D pores along the c direction for accommodation of novel T8(3) water tapes or zigzag water chains. Furthermore, in these compounds, the [Ln(4)(OH)(4)](8+) units and 3-SBA ligands serve as 12-connected and 3-connected nodes, respectively, resulting in a unique (3,12)-connected framework with the Schlafli symbol of (4(3))(4)(4(20).6(28).8(18)). The luminescent properties of the Eu(III) (1) and Tb(III) (3) complexes have been studied, showing characteristic emissions at room temperature. Variable-temperature magnetic susceptibility studies indicate that the Gd(III) complex 2 displays weak antiferromagnetic coupling through mu(3)-OH(-) pathways." @default.
- W2078183713 created "2016-06-24" @default.
- W2078183713 creator A5014277040 @default.
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- W2078183713 creator A5034362915 @default.
- W2078183713 creator A5064019653 @default.
- W2078183713 creator A5079738340 @default.
- W2078183713 date "2010-01-19" @default.
- W2078183713 modified "2023-09-22" @default.
- W2078183713 title "Unique (3,12)-Connected Porous Lanthanide−Organic Frameworks Based on Ln<sub>4</sub>O<sub>4</sub> Clusters: Synthesis, Crystal Structures, Luminescence, and Magnetism" @default.
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- W2078183713 doi "https://doi.org/10.1021/ic902241n" @default.
- W2078183713 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/20085269" @default.
- W2078183713 hasPublicationYear "2010" @default.
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