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• W2078191446 abstract "The reaction between bis(1-pyrazolyl)sulfone (prepared in situ by the reaction between NaH, Hpz, and SOCl2 in THF) and C6H4[C(O)(2-py)]2 in THF catalyzed by CoCl2 yields m-C6H4[C(pz)2(2-py)]2 (1, pz= pyrazolyl, py=pyridyl) in moderate yield, along with 1-[C(pz)2(2-py)]-4-[C(O)(2-py)]C6H4. The potentially bitopic ligand 1 reacts with AgPF6 to yield [Ag(1)2](PF)6 (3), regardless of the stoichiometry of reagents used in the preparation. X-ray structural analysis of this silver complex shows that two ligands bond to a silver in a κ2-fashion via the pyrazolyls in one C(pz)2(py) group in each ligand while the other is non-coordinated. The AgN4C chelate rings adopt a boat conformation and the silver resides in an unusual square planar coordination environment. Non-covalent forces organize the two-dimensional structure of 3 such that it approaches a layered inorganic–organic hybrid material. Reaction of C6H5[C(pz)2(2-py)] and AgPF6 yields {Ag(κ2-C6H5[C(pz)2(2-py)])2}(PF6) (4). The structure is disordered but the ligands are bidentate, the nitrogen donor atoms are in a square planar coordination environment about the silver and the overall structure is similar to 3." @default.
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• W2078191446 date "2004-01-01" @default.
• W2078191446 modified "2023-10-18" @default.
• W2078191446 title "Synthesis of meta-C6H4[C(1-pyrazolyl)2(2-pyridyl)]2, a fixed geometry bitopic heteroscorpionate and the crystal structure of its unusual square planar silver(I) complex" @default.
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• W2078191446 doi "https://doi.org/10.1016/j.poly.2003.11.018" @default.
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