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- W2078201732 abstract "Long-chain alkanoic acids (CH3(CH3)nCO2H, n > 15) form conformationally ordered monolayers on zirconium oxide powder via a chelating bidentate zirconium carboxylate surface bond. ω-Hydroxyalkanoic acids (HO(CH3)15CO2H) produce hydrophilic monolayers, with no evidence of looping to the metal oxide surface. Variable temperature and two-dimensional solid-state NMR experiments demonstrate that alkanoate monolayers display chain dynamics similar to other self-assembled monolayers (SAMs). The thermal behavior of alkanoate SAMs is also compared to analogous fatty acid salt Langmuir−Blodgett monolayers which undergo pretransitional chain disordering." @default.
- W2078201732 created "2016-06-24" @default.
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- W2078201732 date "2000-01-28" @default.
- W2078201732 modified "2023-10-08" @default.
- W2078201732 title "Self-Assembled Monolayers of Alkanoic Acids: A Solid-State NMR Study" @default.
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- W2078201732 doi "https://doi.org/10.1021/la991273e" @default.
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