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• W2078204804 abstract "We investigate a random walk model for describing mixed alkali effects in ionic conductors of the β-alumina type. In our model, the observed drastic variation in the transport properties of the mixed crystals is related to critical properties near a percolation threshold, which originates from the blocking of conduction paths by complexes containing the substituted ions. The motion of a tracer ion and the conductivity are obtained by using the Monte Carlo technique and are discussed in relation to experiments. It is pointed out that anomalous diffusion, which occurs near percolation, leads to a characteristic frequency dependence of the dynamic conductivity, which should be experimentally accessible." @default.
• W2078204804 created "2016-06-24" @default.
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• W2078204804 date "1986-10-01" @default.
• W2078204804 modified "2023-09-23" @default.
• W2078204804 title "Percolation model for mixed alkali effects in solid ionic conductors" @default.
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• W2078204804 doi "https://doi.org/10.1063/1.450884" @default.
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