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- W2078205142 abstract "In the two modifications of TeO2 and in the tellurites two limiting cases for the coordination of oxygen around tellurium are known: on the one hand a 3-coordination in the shape of a trigonal pyramid, and on the other hand a 4-coordination in the shape of a trigonal dipyramid with one of the corners of the equatorial triangel unoccupied. There exist also transitions between the limiting cases; in them Te has a (3 + 1)-coordination. These coordination figures can be linked to groups, chains, sheets, and a framework. The one-sided oxygen coordination around Te(IV) causes relatively “open” structures compared with compounds which contain closed coordination polyhedra only." @default.
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- W2078205142 date "1968-09-01" @default.
- W2078205142 modified "2023-10-18" @default.
- W2078205142 title "The crystal chemistry of the tellurium oxide and tellurium oxosalt minerals" @default.
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- W2078205142 doi "https://doi.org/10.1524/zkri.1968.127.1-4.319" @default.
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