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- W2078207141 abstract "Diffusion of Li+-based and PF6--based species in an amorphous polymer electrolyte has been explored by pulsed-field-gradient (PFG) nuclear magnetic resonance. The experiments were undertaken over a range of salt concentrations and temperature extending to lower values of both variables than in previous studies. Features of the results include a demonstration of different mechanisms for anion and cation transport at high concentration, as shown by their different temperature dependences, a reduced sensitivity of cation diffusion to salt concentration and a failure of the Nernst-Einstein relationship. Cation hopping between ionic clusters and the diffusion of neutral ion pairs are advanced as microscopic mechanisms to explain the data." @default.
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- W2078207141 date "1993-01-11" @default.
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- W2078207141 title "Cation and anion diffusion coefficients in a solid polymer electrolyte measured by pulsed-field-gradient nuclear magnetic resonance" @default.
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- W2078207141 doi "https://doi.org/10.1088/0953-8984/5/2/003" @default.
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