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• W2078208192 abstract "The selectivity of anion-exchange resins in contact with very dilute external solutions (negligible resin invasion by non-exchange electrolyte) is considered due in large part to changes in the solvation of the ions, resulting from differences in the properties of the resin-phase solution and the external dilute aqueous solution. The resin-phase solution is a concentrated electrolyte solution with three significant differences from a dilute electrolyte solution: (a) the cationic species is fixed on the resin matrix; (b) electrostatic forces are stronger; (c) the water molecules in the resin phase have less co-operative structure. The tendency of large univalent ions to be forced out of the dilute solution and into the resin phase because of their small degree of hydration and considerable water-structure-breaking character is considered, as well as the effects of specific group hydration." @default.
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• W2078208192 date "1962-12-01" @default.
• W2078208192 modified "2023-10-06" @default.
• W2078208192 title "On anion-exchange resin selectivities" @default.
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• W2078208192 doi "https://doi.org/10.1016/0022-1902(62)80149-3" @default.
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