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- W2078218105 abstract "Abstract Side‐chain modifications of fullerenes can be achieved starting from the malonic acid 2 , which is easily accessible by saponification of the corresponding diethyl malonate adduct 1 and is therefore an ideal building block for side chain chemistry on fullerenes. Coupling reactions are carried out via the synthesis of the fullerene active ester 4 , which is formed by the reaction of the malonic acid 2 with N ‐hydroxysuccinimide. During this reaction the malonic acid undergoes decarboxylation, yielding an acetic acid derivative instead of a malonic system. The active ester 4 is isolable and represents an ideal building block for fullerene chemistry. Sidechain modifications can also be carried out as one‐step reactions by preparing 4 in situ. We have performed coupling reactions with various compounds containing primary or secondary amino groups." @default.
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- W2078218105 title "Side-Chain Modifications of C60 via Activation of the Easily Accessible Fulleromalonic Acid C61(COOH)2" @default.
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- W2078218105 doi "https://doi.org/10.1002/jlac.199719970136" @default.
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