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- W2078221195 abstract "Model compound reforming studies have been carried out over alumina-supported platinum and iridium catalysts. Cyclohexane and methylcyclopentane were selected to model the dehydrogenation and isomerization-dehydrogenation reactions, respectively, of naphthenes, while, n-heptane was chosen to model paraffin dehydrocyclization. Under typical reforming conditions, the conversion rates and selectivity patterns of these model compounds were found to be highly dependent upon the choice of metal. Platinum, for example, was found to be more active and selective for the aromatization of cyclohexane and methylcyclopentane than iridium. Iridium, in contrast, was observed to be a more active and selective n-heptane dehydrocyclization catalyst than platinum. Synthetic mixtures of model compounds were also investigated. These studies showed that paraffin dehydrocyclization is more strongly retarded by competitive adsorption processes than naphthene aromatization." @default.
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- W2078221195 date "1982-03-01" @default.
- W2078221195 modified "2023-09-28" @default.
- W2078221195 title "Model compound reforming studies: A comparison of alumina-supported platinum and iridium catalysts" @default.
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- W2078221195 doi "https://doi.org/10.1016/0021-9517(82)90019-7" @default.
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