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- W2078221497 abstract "Formaldehyde was passed over various single and binary oxide catalysts in an oxidizing atmosphere. The primary products were methyl formate and formic acid, while, by the consecutive reactions of these products, methanol, CO, and CO2 were formed. The MoO3- and V2O5-based oxides are relatively inactive for the reaction of formaldehyde. Methanol is not obtained with V2O5- and MoO3-containing catalysts. An enhanced yield of formic acid is obtained with V2O5-based catalysts. The best result for the formation of methyl formate is obtained with the SnW = 6733 (atomic ratio) catalyst, which shows a very low activity for the oxidation of methanol. The second-best result is obtained with the SnMo = 7030 catalyst. When the catalysts are a little more basic—for example, pure SnO2, SnO2-K2O, pure Al2O3, Al2O3-K2O, pure Fe2O3, Fe2O3-K2O, and TiO2-K2O, the methyl formate reacting with formaldehyde tends to decompose to methanol and CO2. On the other hand, when the catalysts are a little more acidic—for example, TiO2-WO3 and TiO2-P2O5, the methyl formate tends to decompose to methanol and CO." @default.
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- W2078221497 date "1983-09-01" @default.
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- W2078221497 title "The reaction of formaldehyde on various metal oxide catalysts" @default.
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- W2078221497 doi "https://doi.org/10.1016/0021-9517(83)90037-4" @default.
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