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- W2078222241 abstract "5-Substituierte 3-Trimethylsilyl-1,3,4-oxadiazolin-2-one 6 sind durch Silylierung der entsprechenden 1,3,4-Oxadiazolin-2-one 5 oder durch Silylierung der 3-Acyclcarbazinsaure-phenylester 1 leicht zuganglich. Sie isomerisieren sich nicht zu den 2-Trimethylsiloxy-1,3,4-oxadiazolen 7 und sind thermisch so stabil, das selbst bei Temperaturen von 200–300°C eine Destillation unter Normaldruck moglich ist.Synthesis and Properties of Silylated 1,3,4-Oxadiazolin-2-ones5-Substituted 3-trimethylsilyl-1,3,4-oxadiazolin-2-ones 6 are readily accessible by silylation of the corresponding 1,3,4-oxadiazolin-2-ones 5 or by silylation of phenyl 3-acylcarbazates 1. They do not rearrange to the isomeric 2-trimethylsiloxy-1,3,4-oxadiazoles 7 and their thermal stability permits distillation at 200–300°C under normal pressure." @default.
- W2078222241 created "2016-06-24" @default.
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- W2078222241 date "1973-12-13" @default.
- W2078222241 modified "2023-09-27" @default.
- W2078222241 title "Synthese und Eigenschaften silylierter 1,3,4-Oxadiazolin-2-one" @default.
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- W2078222241 doi "https://doi.org/10.1002/jlac.197319731105" @default.
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