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• W2078224126 startingPage "1343" @default.
• W2078224126 abstract "Abstract Through an unexpected CC bond migration, 2( E )‐enals were efficiently prepared highly stereoselectively in moderate to good yields via the sodium iodide/ tert ‐butyl(dimethyl)silyl chloride (NaI/TBSCl)‐mediated reaction of the easily available 2,3‐allenols. Based on a careful mechanistic study, including control experiments and deuterium‐labeling experiments, an electron‐withdrawing substituent group in the 4 position has been proven to be crucial and a possible mechanism has been proposed. magnified image" @default.
• W2078224126 created "2016-06-24" @default.
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• W2078224126 date "2014-03-17" @default.
• W2078224126 modified "2023-10-18" @default.
• W2078224126 title "Sodium Iodide/<i>tert</i>-Butyl(dimethyl)silyl Chloride-Induced Isomerization of 2,3-Allenols to 2(<i>E</i>)-Enals" @default.
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• W2078224126 doi "https://doi.org/10.1002/adsc.201300835" @default.
• W2078224126 hasPublicationYear "2014" @default.
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