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- W2078231318 abstract "3α-Alkyl-5β-cholestan-2-one (R=CH3, C2H5, and CH3CH2CH2) was prepared by the direct alkylation of 5β-cholestan-2-one with alkyl iodide and potassium t-butoxide in a reflux of t-butyl alcohol-benzene. The 3α-benzyl ketone was prepared from 5β-cholestan-2-one by aldol condensation with benzaldehyde in the presence of potassium hydroxide, followed by hydrogenation of the condensation product. The bromination of these 3α-alkyl ketones gave 3β-bromo-3α-alkyl-5β-cholestan-2-ones." @default.
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- W2078231318 date "1978-01-01" @default.
- W2078231318 modified "2023-10-18" @default.
- W2078231318 title "A-Substituted 5β-Steroids. VIII. Synthesis and Bromination of 3-Alkyl-5β-cholestan-2-one" @default.
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- W2078231318 doi "https://doi.org/10.1246/bcsj.51.192" @default.
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