Matches in SemOpenAlex for { <https://semopenalex.org/work/W2078253685> ?p ?o ?g. }
Showing items 1 to 82 of
82
with 100 items per page.
- W2078253685 endingPage "1784" @default.
- W2078253685 startingPage "1771" @default.
- W2078253685 abstract "In this paper, we revisit the analysis of the classical statistical behavior of three-atom collinear exchange reactions A+BC→AB+C. We begin with the intuitive reason why the statistical assumption (all the states of the available phase space are equiprobable) can, a priori, be applied without any restriction to a collisional process. To check the validity of this hypothesis, we show that an extention of the method of Wagner and Parks allows one to compute the statistical distributions of recoil energy for reactions involving a long lifetime intermediate complex. A comparison between these numerical distributions and the theoretical ones leads to some discrepancies. In order to understand the origin of these unexpected results, we implement a numerical experiment showing that trajectories ‘‘lose the memory’’ of their initial conditions in a reduced area of the region where the three atoms interact. As a consequence, the statistical assumption is only applied in this area which we call the statistical region. The agreement between the resulting theoretical distributions and the numerical ones is now very satisfactory. Thus, the statistical assumption defined above fails. This surprising result shows the originality of the statistical behavior of unbounded systems with a few degrees of freedom, as compared with the larger systems usually treated by statistical mechanics." @default.
- W2078253685 created "2016-06-24" @default.
- W2078253685 creator A5021566169 @default.
- W2078253685 creator A5032676084 @default.
- W2078253685 creator A5078818944 @default.
- W2078253685 date "1993-08-01" @default.
- W2078253685 modified "2023-09-25" @default.
- W2078253685 title "Statistical behavior of elementary collinear exchange reactions<i>A</i>+<i>BC</i>→<i>AB</i>+<i>C</i>" @default.
- W2078253685 cites W1972753654 @default.
- W2078253685 cites W1989695622 @default.
- W2078253685 cites W1999156885 @default.
- W2078253685 cites W2000052480 @default.
- W2078253685 cites W2006111892 @default.
- W2078253685 cites W2053573074 @default.
- W2078253685 cites W2054112238 @default.
- W2078253685 cites W2075213059 @default.
- W2078253685 cites W2092560927 @default.
- W2078253685 cites W4237453987 @default.
- W2078253685 doi "https://doi.org/10.1063/1.465294" @default.
- W2078253685 hasPublicationYear "1993" @default.
- W2078253685 type Work @default.
- W2078253685 sameAs 2078253685 @default.
- W2078253685 citedByCount "7" @default.
- W2078253685 crossrefType "journal-article" @default.
- W2078253685 hasAuthorship W2078253685A5021566169 @default.
- W2078253685 hasAuthorship W2078253685A5032676084 @default.
- W2078253685 hasAuthorship W2078253685A5078818944 @default.
- W2078253685 hasConcept C105795698 @default.
- W2078253685 hasConcept C111472728 @default.
- W2078253685 hasConcept C114289077 @default.
- W2078253685 hasConcept C121332964 @default.
- W2078253685 hasConcept C121864883 @default.
- W2078253685 hasConcept C138885662 @default.
- W2078253685 hasConcept C151342819 @default.
- W2078253685 hasConcept C155560232 @default.
- W2078253685 hasConcept C198394728 @default.
- W2078253685 hasConcept C208081375 @default.
- W2078253685 hasConcept C2986587452 @default.
- W2078253685 hasConcept C33923547 @default.
- W2078253685 hasConcept C48057537 @default.
- W2078253685 hasConcept C62520636 @default.
- W2078253685 hasConcept C64258800 @default.
- W2078253685 hasConcept C75553542 @default.
- W2078253685 hasConcept C99874945 @default.
- W2078253685 hasConceptScore W2078253685C105795698 @default.
- W2078253685 hasConceptScore W2078253685C111472728 @default.
- W2078253685 hasConceptScore W2078253685C114289077 @default.
- W2078253685 hasConceptScore W2078253685C121332964 @default.
- W2078253685 hasConceptScore W2078253685C121864883 @default.
- W2078253685 hasConceptScore W2078253685C138885662 @default.
- W2078253685 hasConceptScore W2078253685C151342819 @default.
- W2078253685 hasConceptScore W2078253685C155560232 @default.
- W2078253685 hasConceptScore W2078253685C198394728 @default.
- W2078253685 hasConceptScore W2078253685C208081375 @default.
- W2078253685 hasConceptScore W2078253685C2986587452 @default.
- W2078253685 hasConceptScore W2078253685C33923547 @default.
- W2078253685 hasConceptScore W2078253685C48057537 @default.
- W2078253685 hasConceptScore W2078253685C62520636 @default.
- W2078253685 hasConceptScore W2078253685C64258800 @default.
- W2078253685 hasConceptScore W2078253685C75553542 @default.
- W2078253685 hasConceptScore W2078253685C99874945 @default.
- W2078253685 hasIssue "3" @default.
- W2078253685 hasLocation W20782536851 @default.
- W2078253685 hasOpenAccess W2078253685 @default.
- W2078253685 hasPrimaryLocation W20782536851 @default.
- W2078253685 hasRelatedWork W1973753516 @default.
- W2078253685 hasRelatedWork W2005002872 @default.
- W2078253685 hasRelatedWork W2058076981 @default.
- W2078253685 hasRelatedWork W2078253685 @default.
- W2078253685 hasRelatedWork W2392619317 @default.
- W2078253685 hasRelatedWork W2393012852 @default.
- W2078253685 hasRelatedWork W2963062232 @default.
- W2078253685 hasRelatedWork W4297970275 @default.
- W2078253685 hasRelatedWork W4301908623 @default.
- W2078253685 hasRelatedWork W74276679 @default.
- W2078253685 hasVolume "99" @default.
- W2078253685 isParatext "false" @default.
- W2078253685 isRetracted "false" @default.
- W2078253685 magId "2078253685" @default.
- W2078253685 workType "article" @default.