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- W2078263395 abstract "Abstract Methylation of chiral acyclic α-methyl-β-ketosulfoxides with Me3Al and Me2AlCl is reported. Induced configuration at hydroxylic carbon is mainly controlled by the configuration of the sulfinyl group, with de's higher than 90% in most of the cases regardless the configuration at C-α. The stereochemical pathway seems to be different with both reagents, thus affording a higher stereoselectivity with Me2AlCl. Pyrolytic desulfinylation and hydrogenolysis of the C–S bond allowed the transformation of the resulting hydroxysulfoxides into interesting optically pure tertiary methyl carbinols." @default.
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- W2078263395 date "2004-06-01" @default.
- W2078263395 modified "2023-09-28" @default.
- W2078263395 title "Asymmetric synthesis of tertiary vinyl carbinols by highly stereoselective methylation of α-methyl-β-ketosulfoxides with aluminum reagents" @default.
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- W2078263395 doi "https://doi.org/10.1016/j.tet.2004.05.016" @default.
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