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- W2078272932 endingPage "963" @default.
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- W2078272932 abstract "The influence of the mobile phase on retention is studied in this paper for a group of over 70 compounds with a broad range of multiple functional groups. We varied the pH of the mobile phase (pH 3, 7, and 10) and the organic modifier (methanol, acetonitrile (ACN), and tetrahydrofuran (THF)), using 15 different stationary phases. In this paper, we describe the overall retention and selectivity changes observed with these variables. We focus on the primary effects of solvent choice and pH. For example, transfer rules for solvent composition resulting in equivalent retention depend on the packing as well as on the type of analyte. Based on the retention patterns, one can calculate selectivity difference values for different variables. The selectivity difference is a measure of the importance of the different variables involved in method development. Selectivity changes specific to the type of analyte are described. The largest selectivity differences are obtained with pH changes." @default.
- W2078272932 created "2016-06-24" @default.
- W2078272932 creator A5009859059 @default.
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- W2078272932 date "2007-05-01" @default.
- W2078272932 modified "2023-10-10" @default.
- W2078272932 title "Selectivity in reversed-phase separations: General influence of solvent type and mobile phase pH" @default.
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- W2078272932 doi "https://doi.org/10.1002/jssc.200600451" @default.
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