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- W2078283576 abstract "Abstract In a previous study about the mechanism of the formation of CdSO4 starting from mechanical mixtures (NH4)2SO4/CdCO3 1 1 M (1), we identified (NH4)2Cd2(SO4)3 as intermediate compound, whose thermal behaviour we have studied. Prymova et al.(2),mention the compound NH4H(SO4)2,stable between 350–450°C,as product of the decomposition of the double sulphate (NH4)2Cd2(SO4)3.However, we have not been able to isolate any intermediate compound during the study of this dissociation. By X-ray analysis of the interval 350–450°C,we identified the diffractions of (NH4)2Cd2(SO4)3,CdSO4 and (NH4)2SO4 with several new lines whose identification is being studied. About 400°C,these lines,that could correspond to a product of the (NH4)2Cd2(SO4)3 decomposition, are the dominant of the diffractogral. The study is carried out by TG, ,DTA, X-ray powder diffraction and IR spectroscopy." @default.
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- W2078283576 date "1985-09-01" @default.
- W2078283576 modified "2023-09-27" @default.
- W2078283576 title "Thermoanalytical study of (NH4)2Cd2(SO4)3, intermediate compound in the heating of the mixture (NH4)2SO4/CdCO3, M" @default.
- W2078283576 doi "https://doi.org/10.1016/0040-6031(85)85927-x" @default.
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